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I have a question

in recent chapters, we find out that hollows are poison to these quincies. i reread the chapter where quilge absorbed ayon and it got me wondering, how did he do it without getting hurt? im sure ayon isnt a type of hollow because he doesn't have a hole on its chest, but it's still some sort of monster created by arrancars.. i'm confused and i'm pretty sure someone can answer this question

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