There have been a lot of speculation for Uryu reason for joining Yhwach and the most common belief is that he is joining them so he can avenge his mother, since Yhwach stole her powers and caused her to die. This is all too familiar as it reminds us of Gin since the whole reason he joined Aizen was so he could kill him because of what he did to Raingiku. Also Yhwach probably knows that Uryu wants to kill him like Aizen knew as well, and also wants to see how Uryu well attempt to try.

(I have a feeling that Ichigo himself is going notice that similarity between Gin and Uryu, and hopefully if this happens, Uryu won't be killed like Gin)

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