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Byakuya Kuchiki is a Shinigami in the world of Bleach, as well as the captain of the 6th Division of the Gotei 13.

Byakuya is first introduced when he is sent the Human World alongside his lieutenant, Renji Abarai, to retrieve his sister Rukia Kuchiki, so that she may face trial in Soul Society. He later faces off against Renji and then against Ichigo Kurosaki, who went to Soul Society to save Rukia. After the betrayal of Sōsuke Aizen, Gin Ichimaru and Kaname Tōsen is brought to light, he makes amends with his sister, Rukia. He then accompanies the Captains Retsu Unohana, Kenpachi Zaraki, and Mayuri Kurotsuchi to Hueco Mundo to aid Ichigo and his friends in rescuing Orihime Inoue from Aizen's Arrancar army. After defeating the 7th Espada Zommari Leroux, he is seen alongside Zaraki taking on the 0 Espada Yammy, so Ichigo can go back to the Human World and protect his town.

Main article: Byakuya Kuchiki

As Ichigo Kurosaki and Retsu Unohana continue through the Garganta, Unohana offers to replenish Ichigo's Reiryoku to return him to full strength. In Hueco Mundo, Kenpachi Zaraki inflicts further injuries on Yammy Riyalgo, and offers Byakuya Kuchiki the chance to finish the Espada off. Byakuya refuses to clean up Zaraki's mess, but the two end up competing to see who can kill Yammy first.

As Kenpachi Zaraki and Byakuya Kuchiki continue fighting, they are interrupted by the arrival of Ashisogi Jizō, who covers the area in his poison mist, allowing Byakuya to return to Muramasa. Soifon fights her Zanpakutō spirit. When the battle ends, Yoruichi Shihōin reveals that she knows the location of the Captain-Commander.